AS 2014 3857
AS 2014 3857
Ordonnance sur la protection contre les substances et les préparations dangereuses (Ordonnance sur les produits chimiques, OChim)
Modification du 17 novembre 2014
L’Office fédéral de la santé publique, en accord avec l’Office fédéral de l’environnement et le Secrétariat d’Etat à l’économie, vu l’art. 97a de l’ordonnance du 18 mai 2005 sur les produits chimiques (OChim)1, arrête:
I L’annexe 7 OChim est remplacée par la version ci-jointe.
II La présente ordonnance entre en vigueur le 1er décembre 2014.
17 novembre 2014 Office fédéral de la santé publique: Pascal Strupler
1 RS 813.11
2014-2403 3857
O sur les produits chimiques RO 2014
Annexe 7
Liste des substances extrêmement préoccupantes («liste des substances candidates»)
Cette liste a été actualisée en dernier lieu le 1er septembre 2014 et comprend 154 substances.
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
1,2,3-Trichloropropane 202-486-1 96-18-4 Carcinogenic and toxic for reproduction 1,2-Benzenedicarboxylic acid, di-C6-8-branched 276-158-1 71888-89-6 Toxic for reproduction alkyl esters, C7-rich 1,2-Benzenedicarboxylic acid, di-C7-11-branched 271-084-6 68515-42-4 Toxic for reproduction and linear alkyl esters 1,2-Benzenedicarboxylic acid, dihexyl ester, 271-093-5 68515-50-4 Toxic for reproduction branched and linear 1,2-Benzenedicarboxylic acid, dipentylester, 284-032-2 84777-06-0 Toxic for reproduction branched and linear 1,2-bis(2-methoxyethoxy)ethane (TEGDME; 203-977-3 112-49-2 Toxic for reproduction triglyme) 1,2-dichloroethane 203-458-1 107-06-2 Carcinogenic 1,2-Diethoxyethane 211-076-1 629-14-1 Toxic for reproduction 1,2-dimethoxyethane; ethylene glycol dimethyl 203-794-9 110-71-4 Toxic for reproduction ether (EGDME) 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane- 219-514-3 2451-62-9 Mutagenic 2,4,6-trione (TGIC) 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5- 423-400-0 59653-74-6 Mutagenic 1-bromopropane (n-propyl bromide) 203-445-0 106-94-5 Toxic for reproduction
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
1-Methyl-2-pyrrolidone 212-828-1 872-50-4 Toxic for reproduction 2,2’-dichloro-4,4’-methylenedianiline 202-918-9 101-14-4 Carcinogenic 2,4-Dinitrotoluene 204-450-0 121-14-2 Carcinogenic 2-Ethoxyethanol 203-804-1 110-80-5 Toxic for reproduction 2-Ethoxyethyl acetate 203-839-2 111-15-9 Toxic for reproduction 2-Methoxyaniline; o-Anisidine 201-963-1 90-04-0 Carcinogenic 2-Methoxyethanol 203-713-7 109-86-4 Toxic for reproduction 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine 421-150-7 143860-04-2 Toxic for reproduction 4-(1,1,3,3-tetramethylbutyl)phenol 205-426-2 140-66-9 Equivalent level of concern having probable serious effects to the environ- ment 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated covering well-defined substances Equivalent level of concern having and UVCB substances, polymers probable serious effects to the environ- and homologues ment 4,4’-Diaminodiphenylmethane (MDA) 202-974-4 101-77-9 Carcinogenic 4,4’-bis(dimethylamino)-4’’-(methylamino)trityl with ≥ 0.1 % of Michler’s ketone 209-218-2 561-41-1 Carcinogenic alcohol (EC No. 202-027-5) or Michler’s base (EC No. 202-959-2) 4,4’-bis(dimethylamino)benzophenone 202-027-5 90-94-8 Carcinogenic (Michler’s ketone) [4-[4,4’-bis(dimethylamino) benzhydrylide- with ≥ 0.1 % of Michler’s ketone 208-953-6 548-62-9 Carcinogenic ne]cyclohexa-2,5-dien-1-ylidene]dimethylam- (EC No. 202-027-5) or Michler’s monium chloride (C.I. Basic Violet 3) base (EC No. 202-959-2) [4-[[4-anilino-1-naphthyl][4-(dimethylamino) with ≥ 0.1 % of Michler’s ketone 19-943-6 2580-56-5 Carcinogenic phenyl]methylene]cyclohexa-2,5-dien-1-ylidene] (EC No. 202-027-5) or Michler’s dimethylammonium chloride (C.I. Basic Blue 26) base (EC No. 202-959-2) 4,4’-methylenedi-o-toluidine 212-658-8 838-88-0 Carcinogenic
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
4,4’-oxydianiline and its salts 202-977-0 101-80-4 Carcinogenic 4-Aminoazobenzene 200-453-6 60-09-3 Carcinogenic 4-methyl-m-phenylenediamine (toluene-2,4- 202-453-1 95-80-7 Carcinogenic diamine) 4-Nonylphenol, branched and linear substances with a linear and/or Equivalent level of concern having branched alkyl chain with a carbon probable serious effects to the environ- number of 9 covalently bound in ment position 4 to phenol, covering also UVCB- and well-defined sub- stances which include any of the individual isomers or a combination thereof 4-Nonylphenol, branched and linear, ethoxylated substances with a linear and/or Equivalent level of concern having branched alkyl chain with a carbon probable serious effects to the environ- number of 9 covalently bound in ment position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homo- logues, which include any of the individual isomers and/or combina- tions thereof 5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) 201-329-4 81-15-2 vPvB 6-methoxy-m-toluidine (p-cresidine) 204-419-1 120-71-8 Carcinogenic Acetic acid, lead salt, basic 257-175-3 51404-69-4 Toxic for reproduction Acids generated from chromium trioxide and 231-801-5, 7738-94-5, Carcinogenic their oligomers. Names of the acids and their 236-881-5 13530-68-2 oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid. Acrylamide 201-173-7 79-06-1 Carcinogenic and mutagenic
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Alkanes, C10-13, chloro (Short Chain 287-476-5 85535-84-8 PBT and vPvB Chlorinated Paraffins) Aluminosilicate Refractory Ceramic Fibres are fibres covered by index – Extracted from Carcinogenic number 650-017-00-8 in Index no.: Annex VI, part 3, table 3.2 of 650-017-00-8 Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December
2008 on classification, labelling
and packaging of substances and mixtures, and fulfil the two follow- are present within the following concentration ranges:Al2O3: 43.5– 48.5–54 % w/w,b) fibres have a length weighted geometric mean diameter less two standard geomet- ric errors of 6 or less micrometres (µm). Ammonium dichromate 232-143-1 7789-09-5 Carcinogenic, mutagenic and toxic for reproduction Ammonium pentadecafluorooctanoate (APFO) 223-320-4 3825-26-1 Toxic for reproduction Anthracene 204-371-1 120-12-7 PBT Anthracene oil 292-602-7 90640-80-5 Carcinogenic[1], PBT and vPvB Anthracene oil, anthracene paste 292-603-2 90640-81-6 Carcinogenic[2], mutagenic[3], PBT and vPvB Anthracene oil, anthracene paste, anthracene 295-275-9 91995-15-2 Carcinogenic[2], mutagenic[3], fraction PBT and vPvB
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Anthracene oil, anthracene paste,distn. lights 295-278-5 91995-17-4 Carcinogenic[2], mutagenic[3], PBT and vPvB Anthracene oil, anthracene-low 292-604-8 90640-82-7 Carcinogenic[2], mutagenic[3], PBT and vPvB Arsenic acid 231-901-9 7778-39-4 Carcinogenic Benzyl butyl phthalate (BBP) 201-622-7 85-68-7 Toxic for reproduction Biphenyl-4-ylamine 202-177-1 92-67-1 Carcinogenic Bis (2-ethylhexyl)phthalate (DEHP) 204-211-0 117-81-7 Toxic for reproduction Bis(2-methoxyethyl) ether 03-924-4 111-96-6 Toxic for reproduction Bis(2-methoxyethyl) phthalate 204-212-6 117-82-8 Toxic for reproduction Bis(pentabromophenyl) ether (decabromodiphenyl 214-604-9 1163-19-5 PBT ether; DecaBDE) Bis(tributyltin)oxide (TBTO) 200-268-0 56-35-9 PBT Boric acid 233-139-2/ 10043-35-3/ Toxic for reproduction 234-343-4 11113-50-1 Cadmium 231-152-8 7440-43-9 Carcinogenic Cadmium chloride 233-296-7 10108-64-2 Carcinogenic, Mutagenic, Toxic for reproduction and Equivalent level of concern having probable serious effects to human health Cadmium oxide 215-146-2 1306-19-0 Carcinogenic Cadmium sulphide 215-147-8 1306-23-6 Carcinogenic Calcium arsenate 231-904-5 7778-44-1 Carcinogenic
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Chromium trioxide 215-607-8 1333-82-0 Carcinogenic and mutagenic Cobalt dichloride 231-589-4 7646-79-9 Carcinogenic and toxic for reproduction Cobalt(II) carbonate 208-169-4 513-79-1 Carcinogenic and toxic for reproduction Cobalt(II) diacetate 200-755-8 71-48-7 Carcinogenic and toxic for reproduction Cobalt(II) dinitrate 233-402-1 10141-05-6 Carcinogenic and toxic for reproduction Cobalt(II) sulphate 233-334-2 10124-43-3 Carcinogenic and toxic for reproduction Diarsenic pentaoxide 215-116-9 1303-28-2 Carcinogenic Diarsenic trioxide 215-481-4 1327-53-3 Carcinogenic Diazene-1,2-dicarboxamide (C,C’- 204-650-8 123-77-3 Equivalent level of concern having azodi(formamide)) probable serious effects to human health Diboron trioxide 215-125-8 1303-86-2 Toxic for reproduction Dibutyl phthalate (DBP) 201-557-4 84-74-2 Toxic for reproduction Dibutyltin dichloride (DBTC) 211-670-0 683-18-1 Toxic for reproduction Dichromium tris(chromate) 246-356-2 24613-89-6 Carcinogenic Diethyl sulphate 200-589-6 64-67-5 Carcinogenic; Mutagenic Dihexyl phthalate 201-559-5 84-75-3 Toxic for reproduction Diisobutyl phthalate 201-553-2 84-69-5 Toxic for reproduction Diisopentylphthalate 210-088-4 605-50-5 Toxic for reproduction Dimethyl sulphate 201-058-1 77-78-1 Carcinogenic Dinoseb (6-sec-butyl-2,4-dinitrophenol) 201-861-7 88-85-7 Toxic for reproduction Dioxobis(stearato)trilead 235-702-8 12578-12-0 Toxic for reproduction Disodium 3,3’-[[1,1’-biphenyl]-4,4’- 209-358-4 573-58-0 Carcinogenic diylbis(azo)]bis(4-aminonaphthalene-1-sulphonate) (C.I. Direct Red 28)
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Disodium 4-amino-3-[[4’-[(2,4- 217-710-3 1937-37-7 Carcinogenic diaminophenyl)azo][1,1’-biphenyl]-4-yl]azo] -5- hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate (C.I. Direct Black 38) Disodium tetraborate, anhydrous 215-540-4 1303-96-4/ Toxic for reproduction 1330-43-4/ 12179-04-3 Dipentyl phthalate (DPP) 205-017-9 131-18-0 Toxic for reproduction Fatty acids, C16-18, lead salts 292-966-7 91031-62-8 Toxic for reproduction Formaldehyde, oligomeric reaction products 500-036-1 25214-70-4 Carcinogenic with aniline Formamide 200-842-0 75-12-7 Toxic for reproduction Furan 203-727-3 110-00-9 Carcinogenic Henicosafluoroundecanoic acid 218-165-4 2058-94-8 vPvB Heptacosafluorotetradecanoic acid 206-803-4 376-06-7 vPvB Hexabromocyclododecane (HBCDD) and Alpha-hexabromocyclododecane 247-148-4 and 25637-99-4 PBT all major diastereoisomers identified: Beta-hexabromocyclododecane 221-695-9 3194-55-6 (134237-50-6) Gamma-hexabromocyclododecane (134237-51-7) (134237-52-8) Hexahydromethylphthalic anhydride [1], The individual isomers [2], [3] and 247-094-1, 25550-51-0, Equivalent level of concern having Hexahydro-4-methylphthalic anhydride [2], [4] (including their cis- and trans- 243-072-0, 9438-60-9, probable serious effects to human health stereo isomeric forms) and all Hexahydro-1-methylphthalic anhydride [3], possible combinations of the 256-356-4, 48122-14-1, Hexahydro-3-methylphthalic anhydride [4] isomers [1] are covered by this 260-566-1 7110-29-9 entry Hydrazine 206-114-9 302-01-2/ Carcinogenic 7803-57-8 Imidazolidine-2-thione (2-imidazoline-2-thiol) 202-506-9 96-45-7 Toxic for reproduction
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Lead bis(tetrafluoroborate) 237-486-0 13814-96-5 Toxic for reproduction Lead chromate 231-846-0 7758-97-6 Carcinogenic and toxic for reproduction Lead chromate molybdate sulphate red 235-759-9 12656-85-8 Carcinogenic and toxic for reproduction (C.I. Pigment Red 104) Lead cyanamidate 244-073-9 20837-86-9 Toxic for reproduction Lead di(acetate) 206-104-4 301-04-2 Toxic for reproduction Lead diazide, Lead azide 236-542-1 13424-46-9 Toxic for reproduction Lead dinitrate 233-245-9 10099-74-8 Toxic for reproduction Lead dipicrate 229-335-2 6477-64-1 Toxic for reproduction Lead hydrogen arsenate 232-064-2 7784-40-9 Carcinogenic and toxic for reproduction Lead monoxide (lead oxide) 215-267-0 1317-36-8 Toxic for reproduction Lead oxide sulfate 234-853-7 12036-76-9 Toxic for reproduction Lead styphnate 239-290-0 15245-44-0 Toxic for reproduction Lead sulfochromate yellow (C.I. Pigment 215-693-7 1344-37-2 Carcinogenic and toxic for reproduction Yellow 34) Lead titanium trioxide 235-038-9 12060-00-3 Toxic for reproduction Lead titanium zirconium oxide 235-727-4 12626-81-2 Toxic for reproduction Lead(II) bis(methanesulfonate) 401-750-5 17570-76-2 Toxic for reproduction Methoxyacetic acid 210-894-6 625-45-6 Toxic for reproduction Methyloxirane (Propylene oxide) 200-879-2 75-56-9 Carcinogenic; Mutagenic N,N,N’,N’-tetramethyl-4,4’-methylenedianiline 202-959-2 101-61-1 Carcinogenic (Michler’s base) N,N-dimethylacetamide 204-826-4 127-19-5 Toxic for reproduction N,N-dimethylformamide 200-679-5 68-12-2 Toxic for reproduction N-methylacetamide 201-182-6 79-16-3 Toxic for reproduction
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Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
N-pentyl-isopentylphthalate - 776297-69-9 Toxic for reproduction o-aminoazotoluene 202-591-2 97-56-3 Carcinogenic Orange lead (lead tetroxide) 215-235-6 1314-41-6 Toxic for reproduction o-Toluidine 202-429-0 95-53-4 Carcinogenic Pentacosafluorotridecanoic acid 276-745-2 72629-94-8 vPvB Pentadecafluorooctanoic acid (PFOA) 206-397-9 335-67-1 Toxic for reproduction Pentalead tetraoxide sulphate 235-067-7 12065-90-6 Toxic for reproduction Pentazinc chromate octahydroxide 256-418-0 49663-84-5 Carcinogenic Phenolphthalein 201-004-7 77-09-8 Carcinogenic [Phthalato(2-)]dioxotrilead 273-688-5 69011-06-9 Toxic for reproduction Pitch, coal tar, high temp. 266-028-2 65996-93-2 Carcinogenic, PBT and vPvB Potassium chromate 232-140-5 7789-00-6 Carcinogenic and mutagenic Potassium dichromate 231-906-6 7778-50-9 Carcinogenic, mutagenic and toxic for reproduction Potassium hydroxyoctaoxodizincatedichromate 234-329-8 11103-86-9 Carcinogenic Pyrochlore, antimony lead yellow 232-382-1 8012-00-8 Toxic for reproduction Silicic acid (H2Si2O5), barium salt (1:1), lead-doped with lead (Pb) content above the 272-271-5 68784-75-8 Toxic for reproduction applicable generic concentration limit for ’toxicity for reproduction’ Repr. 1A (CLP) or category 1 (DSD); the substance is a member of the group entry of lead com- pounds, with index number 082- 001-00-6 in Regulation (EC) No Silicic acid, lead salt 234-363-3 11120-22-2 Toxic for reproduction
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Sodium chromate 231-889-5 7775-11-3 Carcinogenic, mutagenic and toxic for reproduction Sodium dichromate 234-190-3 7789-12-0/ Carcinogenic, mutagenic and toxic for 10588-01-9 reproduction Sodium perborate; perboric acid, sodium; salt 239-172-9; – Toxic for reproduction 234-390-0 Sodium peroxometaborate 231-556-4 7632-04-4 Toxic for reproduction Strontium chromate 232-142-6 7789-06-2 Carcinogenic Sulfurous acid, lead salt, dibasic 263-467-1 62229-08-7 Toxic for reproduction Tetraboron disodium heptaoxide, hydrate 235-541-3 12267-73-1 Toxic for reproduction Tetraethyllead 201-075-4 78-00-2 Toxic for reproduction Tetralead trioxide sulphate 235-380-9 12202-17-4 Toxic for reproduction Trichloroethylene 201-167-4 79-01-6 Carcinogenic Tricosafluorododecanoic acid 206-203-2 307-55-1 vPvB Triethyl arsenate 427-700-2 15606-95-8 Carcinogenic Trilead bis(carbonate)dihydroxide 215-290-6 1319-46-6 Toxic for reproduction Trilead diarsenate 222-979-5 3687-31-8 Carcinogenic and toxic for reproduction Trilead dioxide phosphonate 235-252-2 12141-20-7 Toxic for reproduction Tris(2-chloroethyl)phosphate 204-118-5 115-96-8 Toxic for reproduction Trixylyl phosphate 246-677-8 25155-23-1 Toxic for reproduction
O sur les produits chimiques RO 2014
Nom de la substance Informations complémentaires sur la No CE No CAS Raison de l’inclusion dans la liste substance
Zirconia Aluminosilicate Refractory are fibres covered by index – Extracted from Carcinogenic Ceramic Fibres number 650-017-00-8 in Index no. Annex VI, part 3, table 3.2 of 650-017-00-8 Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December
2008 on classification, labelling
and packaging of substances and mixtures, and fulfil the two follow- ZrO2 are present within the follow- ing concentration ranges: Al2O3: 15–17 % w/w, b) fibres have a length weighted geometric mean diameter less two standard geomet- ric errors of 6 or less micrometres (µm). α,α-Bis[4-(dimethylamino)phenyl]-4- with ≥ 0.1 % of Michler’s ketone 229-851-8 6786-83-0 Carcinogenic (phenylamino)naphthalene-1-methanol (EC No. 202-027-5) or Michler’s (C.I. Solvent Blue 4) base (EC No. 202-959-2)
[*] The EC number includes both anhydrous and hydrated forms of a substance and consequently the entries cover both these forms. The CAS number included may be for the anhydrous form only, and therefore the CAS number shown does not always describe the entry accurately. [1] The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) [2] The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) and less than 0,1 % w/w benzene (EINECS No 200-753-7).]